 If you liked
Shakugan no Shana
|
 ...then you might like
Claymore
|
Both shows revolve around a group of warriors who fight enigmatic creatures prone to preying on humanity. The heroines (Shana and Clare) are introduced as cold warriors who prioritize their duties over protecting the innocent but after meeting a weak but kind human boy (Yuuji and Raki) they defrost and become more heroic.
Both shows are also quite dark in tone, though "Claymore" is definitely the darker of the two.
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Recommended by Joe_Devaney